RESUMO
This study investigates the origin of low-pressure hysteresis (LPH) in the adsorption and desorption of three different probe molecules: carbon dioxide, nitrogen, and argon, across various adsorption temperatures (from cryogenic to room temperature), and within five different carbon materials: synthetic carbons (pristine and one post-synthetically oxidized) and natural coal. Significant attention is dedicated to elucidating LPH in oxidized samples outgassed at various temperatures (120-350 °C). Experimental results show that insufficient outgassing temperature can lead to unreliable data due to artificial LPH and significantly underestimated textural properties, primarily caused by porosity blockage from substances like moisture. Conversely, in samples where heteroatoms have a stabilizing effect on texture, such as natural coal, careful consideration of outgassing temperature is crucial due to the risk of thermal degradation. Other factors contributing to LPH are adsorption temperature, and especially, kinetic limitations at cryogenic temperatures for cellulose-based carbons. Minor factors responsible for LPH are the physical state of the sample (monolith vs powder) and the flexibility of the porous system, both studied by carbon dioxide sorption. This study constitutes an important piece in the evaluation of LPH, providing practical recommendations and underlining the importance of experimental design, with implications for further research in this complex field.
RESUMO
This study evaluates the removal of several dyes with different charge properties, i.e., anionic (Acid Red 88), cationic (Basic Red 13), and neutral (Basic Red 5) using transition metal-doped TiO2 supported on a high-surface-area activated carbon. Experimental results confirm the successful deposition of TiO2 and the derivatives (Zr-, Cu-, and Ce-doped samples) on the surface of the activated carbon material and the development of extended heterojunctions with improved electronic properties. Incorporating a small percentage of dopants significantly improves the adsorption properties of the composites towards the three dyes evaluated, preferentially for sample AC/TiO2_Zr. Similarly, the photodegradation efficiency highly depends on the nature of the composite evaluated and the characteristics of the dye. Sample AC/TiO2_Zr demonstrates the best overall removal efficiency for Acid Red 88 and Basic Red 5-83% and 63%, respectively. This promising performance must simultaneously be attributed to a dual mechanism, i.e., adsorption and photodegradation. Notably, the AC/TiO2_Ce outperformed the other catalysts in eliminating Basic Red 13 (74%/6 h). A possible Acid Red 88 degradation mechanism using AC/TiO2_Zr was proposed. This study shows that the removal efficiency of AC/TiO2 composites strongly depends on both the material and pollutant.
